Fragrance Carrier Based on Zeolite-A Modified Bentonite as a Controlled Release System in Air Freshener Applications; [Pembawa Wangian Berdasarkan Zeolite-A Bentonit Terubah Suai sebagai Sistem Pelepasan Terkawal dalam Aplikasi Penyegar Udara]

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Eny Kusrini, Anwar Usman, Karina Ayuningtyas, Lee D. Wilson, Nandy Putra, Agus Budi Prasetyo, Arif Rahman, Khoirina Dwi Nugrahaningtyas, Sri Juari Santosa, Atiek Rostika Noviyanti

2024 Sains Malaysiana Vol. 53 Issue 10 Article Cited by 2 SDG 12SDG 17 Quartile

Abstract

The quality of air fresheners with low cost production can be improved by using a carrier matrix such as synthetic zeolite to increase the long-lasting properties of fragrance product by encapsulation technique. The zeolite A is considerd as a safe core fragrance carrier matrix to be able to release volatile fragrance from their pores when exposed to atmospheric humidity at room temperature. Zeolite A was synthesized from natural kaolin and was formed into tube pellets with bentonite (20 wt.%) as binder to produce zeolite A-bentonite (ZAB) cylindrical pellets composite and used as a fragrance carrier matrix with a rose essential oil (Rose damascena Mill.) as parfume model. The fresh bentonite can also adsorb the rose essential oil with adsorption capacity of 1.745 g/g bentonite (74.5%). Effects of chemical activation on zeolite-A using acid (HCl) of 0.1 M and base (NaOH) of 0.1 M were studied. The ZAB tube pelletes were found to have high adsorption efficiencies of rose essential oil. ZAB4 has the highest efficiency and was used for regeneration test studies that was carried out over 10 cycles using HCl and NaOH, where the adsorption efficiency was 94.5 and 75.4%, respectively. The activated ZAB4 composite using HCl has a long life time until more than 5 weeks and more than 10 regeneration cycles. This fragrance carrier matrix based on ZAB has significant potential for extended carrier fragrance system. © 2024 Penerbit Universiti Kebangsaan Malaysia. All rights reserved.

Affiliations

Department of Chemical Engineering, Universitas Indonesia, Kampus Baru UI, Depok, 16424, Indonesia; Green Product and Fine Chemical Engineering Research Group, Laboratory of Chemical Product Engineering, Universitas Indonesia, Kampus Baru UI, Depok, 16424, Indonesia; Tropical Renewable Energy Research Center, Faculty of Engineering, Universitas Indonesia, Kampus Baru UI, Depok, 16424, Indonesia; Department of Chemistry, Faculty of Science, Universiti Brunei Darussalam, Jalan Tungku Link, Negara Brunei Darussalam, Gadong, BE1410, Brunei Darussalam; Department of Chemistry, University of Saskatchewan, 110 Science Place, Thorvaldson Building, Saskatoon, S7N 5C9, SK, Canada; Department of Mechanical Engineering, Universitas Indonesia, Kampus Baru UI, Depok, 16424, Indonesia; Research Center for Metallurgy, National Research and Innovation Agency (BRIN), KST, BJ. Habibie, Puspitek Area, Setu, Tangerang Selatan, 15314, Indonesia; Department of Chemistry, Faculty of Mathematic and Natural Sciences, Universitas Negeri Jakarta, Jakarta Timur, 13220, Indonesia; Department of Chemistry, Faculty of Mathematics and Natural Sciences, Sebelas Maret University, Jl. Ir Sutami No. 36A, Surakarta, 57126, Indonesia; Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara P.O. Box BLS 21, Yogyakarta, 55281, Indonesia; Department of Chemistry, Faculty of Mathematics and Natural Sciences, Padjadjaran University, Jl. Raya Bandung Sumedang km 21, Jatinangor, Indonesia

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