Shock wave plasma generation in low pressure ambient gas from powder sample using subtarget supported micro mesh as a sample holder and its potential applications for sensitive analysis of powder samples

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Javed Iqbal, Marincan Pardede, Eric Jobiliong, Rinda Hedwig, Muliadi Ramli, Ali Khumaeni, Wahyu Setia Budi, Nasrullah Idris, Syahrun Nur Abdulmadjid, Kurnia Lahna, Mangasi Alion Marpaung, Indra Karnadi, Zener Sukra Lie, Hery Suyanto, Davy Putra Kurniawan, Tjung Jie Lie, Koo Hendrik Kurniawan, Kiichiro Kagawa, May On Tjia

2018 Microchemical Journal Vol. 142 Article Cited by 13 SDG 7SDG 17 Quartile

Abstract

We present in this report the results of experimental study on the spectrochemical analysis of powder samples using subtarget supported micro mesh (SSMM) sample holder in low pressure ambient gases. The study is substantiated by establishing the analyte excitation mechanism with the evidence of shock wave plasma generation and the high temperature induced subsequently required for the thermal excitation and emission of the ablated atoms. The application of SSMM sample holder using Cu subtarget and stainless steel micro mesh to a number of powder samples in low pressure ambient gases are shown to produce generally sharp emission lines with low background, without suffering from intensity reduction and matrix effect commonly found in the use of pelletized powder samples. The same excellent spectral quality is demonstrated by its application to the analysis of rice samples which is the major staple diets in a large number of countries. In particular the analysis of Zn in rice is shown to exhibit a linear calibration line with extrapolated zero intercept and a detection limit of <0.87 μg/g which is promising for quantitative analysis. © 2018

Affiliations

Department of Physics, University of Azad, Jammu & Kashmir, Muzaffarabad, Pakistan; University of Pelita Harapan, 1100 M.H. Thamrin Boulevard, Lippo Village, Tangerang, 15811, Indonesia; Department of Computer Engineering, Bina Nusantara University, 9 K.H. Syahdan, Jakarta, 14810, Indonesia; Faculty of Mathematics and Natural Sciences, Syiah Kuala University, Darussalam, Banda Aceh, 23111, Indonesia; Faculty of Mathematics and Natural Sciences, Diponegoro University, Tembalang, Semarang, 50275, Indonesia; Faculty of Mathematics and Natural Sciences, Jakarta State University, 10 Rawamangun, Jakarta, Indonesia; Krida Wacana Christian University, Jakarta, 11470, Indonesia; Faculty of Mathematics and Natural Sciences, Udayana University, Kampus Bukit Jimbaran, Denpasar, 80361, Bali, Indonesia; Research Center of Maju Makmur Mandiri Foundation, 40/80 Srengseng Raya, Jakarta, 11630, Indonesia; Fukui Science Education Academy, Takagi Chuou 2 choume, Fukui, 910-0804, Japan; Physics of Magnetism and Photonics Group, Faculty of Mathematics and Natural Sciences, Bandung Institute of Technology, 10 Ganesha, Bandung, 40132, Indonesia

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