Post-annealing effect on optical absorbance of hydrothermally grown zinc oxide nanorods

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Rahmat Setiawan Mohar, S. Iwan, Dede Djuhana, Cuk Imawan, Adhi Harmoko, Vivi Fauzia

2016 AIP Conference Proceedings Vol. 1729 Conference paper Cited by 20 SDG 17SDG 14SDG 7SDG 9 Quartile

Abstract

In this study, the optical absorbance of zinc oxide (ZnO) nanorods was investigated. The ZnO thin film were deposited on indium tin oxide (ITO) layers using ultrasonic spray pyrolysis (USP) method and then grown by hydrothermal method. In order to improve the optical absorbance, the ZnO nanorods were then post-annealed for one hour at three different of temperatures, namely 250, 400, and 500 °C. The X-ray diffraction (XRD) spectra and FESEM images show that the ZnO nanorods have the hexagonal wurtzite crystal structure and the increasing of post-annealing temperature resulted in the increasing of crystallite size from 38.2 nm to 48.4 nm. The UV-vis spectra shows that all samples of ZnO nanorods exhibited the identical sharp absorption edge at 390 nm indicating that all samples have the same bandgap. The post-annealing process seemed to decrease the optical absorbance in the region of 300-550 nm and increase the optical absorbance in the region of 550-700 nm. © 2016 Author(s).

Affiliations

Departemen Fisika, Universitas Indonesia, FMIPA, Indonesia; Jurusan Fisika, Fakultas MIPA, Universitas Negeri Jakarta, Jakarta, 13220, Indonesia

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